Dr. Gulden Yilmaz, Gerrit Gerritsen WUR-Food and Biobased Research, IPSS engineering

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1 Dr. Gulden Yilmaz, Gerrit Gerritsen WUR-Food and Biobased Research, IPSS engineering

2 Bioeconomy New Value Chains based on co-production of food and non-food products Source: Mosmuller, BFF 2013

3 A new balance Biorefinery kg + kj k

4 What is biorefinery? Biorefinery is the tailor made separation of biomass into its components

5 The Onion

6 Bioeconomy is niet nieuw! Hair Wool Riet Linnen Glues Wood Jute Textile Coconuts Paper Leather Rubber Cotton Paints As old as the humanity!

7 Dutch Roadmap Biorefinery Title: Opportunities for Dutch Biorefineries (2009) Integrated approach Four possible routes (moonshots) towards biorefinery in NL Combines short- & medium-term possibilities h=p://edepot.wur.nl/50725

8 Four different Moonshots in NL Roadmap M1. Specific domestic crops M2. Aquatic biomass M3. Imported biomass M4. Residue streams h=p://edepot.wur.nl/50725

9 M1. YXY Technology (Avantium) Chemical Catalysis Biorefinery Pilot plant in Geleen Feed stocks: cellulose, hemi-cellulose, starch, sucrose Outputs: Furan based biofuels, monomers for polymers, chemicals, solid fuels h=p://avaneum.com/yxy/yxy- technology/yxy- process- technology.html

10 M2. AlgaeParc An oil production and refinery pilot-plant for Omega-3, fuels, chemicals from microalgae in Wageningen h=p://www. wageningenur.nl/en/experese- Services/FaciliEes/ AlgaePARC.htm

11 M4. BioMCN (2010) Upgrading of biodiesel byproduct glycerin to biomethanol for transport Plant in Delfzijl opened officially on 25th of June 2010 Production capacity of 250 million litres h=p://

12 M4. Ecoson (2013) Integrated production of biogas, and biodiesel from animal waste Production capacity per year: - 9,000 MWh from biogas - 50,000 ton refined fat - 5,000 ton biodiesel h=p://

13 M4. Empyro commercial pyrolysis plant (2014) Construction pyrolysis plant (started in 2014) Consist of modules/skids Feedstock e.g. wood chips Production of 20 million litres of pyrolysis oil/ year Pyrolysis oil used for bioenergy and chemicals h=p://www. empyroproject.eu

14 It begins with energy Regulations Existing infrastructure Proven technology Profitability? Towards multiproduct approach

15 Added Value High value Pharma & cosmetics Food & Feed Bioplastics & Polymers Bulk chemicals & Fuels Energy & Heat Low value

16 Complete valorisation Focus Platforms Lignocellulose Fresh biomass Aquatic biomass Traditional crops Crops Byproducts New biomass Pre-treatment & Separation/ Isolation Proteins Fibres Sugars Oils&fats (Bio)chemical & Conversion Markets Feed&Food Materials Chemicals Energy & Fuels Biomass chain aspects: availability, quality, sustainability, logistics

17 Rapeseed meal /GJ Wood chips Straw (field) Straw (collected) Straw (washed) Rape meal Multiproduct biorefinery /ton Protein Animal feed Amino acids Ferment. substrates Lignocellulose Fibres Phosphorus Rest By prof. Johan Sanders

18 Grass Fresh grass Fibers 30 % 100 Oligo- saccharides 3% 1500 Lipids 3 % 2000 water % Organic acids 5% 2000 Mono/di- saccharides 150 Protein / Amino acids 20 % 1000 Minerals 10 % dry substance 10-20% By prof. Johan Sanders Polysaccharides 15 % 1500

19 Biorefinery toolbox Harvesting Pre-treatment & Fractionation Separation/ isolation DSP Centrifugation Filtration Sedimentation Flocculation Dewatering Disruption Pressing Homogenizing Extraction Centrifugation Precipitation Drying Preservation Conversion Biotechnology Chemistry Polymer processing

20 Economy of scale Many new processes are required for adaptation and mitigation This also holds for the Bio-economy processes. Introduction of new processes represent considerable risks

21 Byosis/Zeafuels (Lelystad, Netherlands)full scale

22 Mobile unit Grassa (Friesland, NL); for a variety of leaves (Status= Pilot scale) Grass protein (products) white grass protein Protein compound feed Green grass protein Grass juice concentrate Grass juice Fibers compound feed Ethanol +... HTU- Biofuel ConstrucHon material + paper By prof. Johan Sanders Polymer extrusion products

23 Sugar crystallisation Sucrose Amino acids Sugar beets Sugar cane Sugar palm Lactose Other sugars * DLP Black liquor Chicory Beet pulp Grass juice Protamylasse Grass juice Corn steep liquor/cds New technology using a nonsolvent approach Location on site; water, leaf and other valuable minerals remain on site for recovery, which can also lead to transport reductions; Higher purity in fewer process steps; Feasibility demonstrated Scaled up to pilot scale (IPSS) Especially interesting for the upcoming demand in de chemical industry

24 IPSS Engineering De engineering partner voor ondersteuning, ontwikkeling en optimalisatie van bio-based processen en productie installaties. Wij bieden totaal oplossingen van onderzoeksfase tot en met constructie.

25 Innovatief kristallisatie proces Innovatief proces Wageningen UR Door toevoeging anti-oplosmiddel Worden suikers minder oplosbaar Suikerbieten Tuinbouw resten Met suikerkristallen als resultaat Toepasbaar op: (Berm)- grassen DLP (zuivel) Black Liquor (papier) Energiebieten

26 R&D installatie Impressie van R&D installatie 20ft container

27 Fasen innovatieve kristallisatie Fase 1 Wassen, snijden en diffusie proces Fase 2 Indampen Fase 3 Kristallisatie Fase 4 Verdeling restproducten Diervoeding Consumenten suiker Meststof Biogas Grondstof voor o.a. kunststoffen Biogas Snijdsel/ Tarra Diksap Suiker 17% Vinasse 2,4% Suikerbiet 9,2 ton / h 0,12 ha / h Ruwsap (SBJ) Water + 17% suiker Onzuiverheden Melasse 3,5% (50% suiker) Alcohol 1% Pulp 6,9 % (88% droog) Gist 0,5% Diervoeding Toepassingen in Verpakkingen (plastics) andere producten Biogas Uitrijden over land

28 Productie Plant Busness Case Qing Sustainable Totaal (k ) Totale investering Per ton suiker ( / ton) Per jaar (k ) Totale opbrengsten Totale kosten EBIT Capaciteit: 314 ha in 12 weken; 9,5 ton/uur Investeringskosten: 1 M Terugverdien tijd: ca. 6 jaar

29 Productie Plant

30 Voordelen op locatie Toepasbaar op grondstofstromen met verontreinigingen ü suikerbieten ü Tuinbouw resten ü DLP (zuivel) ü Black Liquor (papier) ü Energiebieten etc.) Eenvoudig proces, daardoor compact en verplaatsbaar Energiezuinig door hergebruik van grondstoffen, energie en proceswarmte Mogelijkheid tot productie van biogas en bio-ethanol

31 Voordelen op locatie Meer inkomsten boer Beperking transport door lokale verwerking Water aarde en loof blijven op het land (verrijking) Volledig geautomatiseerde bediening

32 Contact Gulden Yilmaz Tel: : gulden.yilmaz@wur.nl Gerrit Gerritsen Tel: : ggerritsen@ipss.nl